I do - Nothing in my little fleet is less than 5 years old - my TDI is five an a half now, though that's not old enough to be affected by this. However, two of them are old enough that this whole ZDDP thing is preying on my mind.scorpio_vette said:does anybody in todays world even keep their vehicle or engine long enough to care???
RyanM said:Lucas and its 5ppm of zinc
mikegronholz said:No sooner did i post that she isn't "crying" than i crawl underneath and find a "film" :doh: ... so this weekend .. out with the syn, and in with the dino. i think I am going to do dino Rotella and a bottle of Lucas.
Sure ... there are 2 major frames of thought ...JNickel101 said:Anyone care to summerize this "short" thread?
I'm in the USAF, and at our Auto Shop, they have a pretty big selection of oils....was looking and most were SM and SL.....the RP 10w40 was only SL....but their 10w30 was SM/SL....Castrol GTX was also SM/SL.....
OK since you have problem with the word "thickness" let's call it surface density to be more precise. Surface density being defined as the number of molecules, or moles per unit surface area. The higher the ZDDP concentration (up to about .19% as the upper limit point from what I recall reading) the higher the surface density of ZDDP molecules in potentially high wear areas, and thus the less wear in those areas.geeaea said:Ecomike,
ZDDP is sacrificial ...there is no "thickness" to it. If you happen to have a surface break through the hydrodynamic layer ...zddp is there to "throw itself in harm's way".
In your analysis you assume that only a certain amount of zddp can be in "decay mode" at any given time. But is that the case? Maybe the higher levels of zddp would equate to higher ppm of it being decayed at any given time. Meaning more of it is in use. I'm just thinking out loud here, but until someone can show that, regardless of the % of zddp in the system, only a finite amount of it can be in "use" at any given time/point, your argument might not be valid.geeaea said:Mike ...there is a decay rate. The incremental or decremental aspect of it can only manifest itself in length of service. Think about it.
If you admit that zddp is sacrificial ...(enough evidence for anyone to accept) ..then there is a point where there is less of it (in its usable form = there's no "uptake" of the fundamental zinc and phos = they do, however, volatilize). That sensibly leads most to reason that a 1200 ppm starting point ....or a 900 ppm starting point are GOING to resemble each other in effective worth AT SOME POINT in the OCI.
We then would sensibly reason that it's down to a matter of length of OCI that will determine your TRUE level of viable zddp in the oil. Naturally, if you start with more ...you'll end with more ...but you'll be dealing with "less" of it from the first time you bump the key ..and every revolution after that until you drain it out.
Go ahead and put both levels (900/1200) on any decay curve that you want. Use exponential if you want. Now plot that over a given mileage (make it up) ..there IS - by any reasonable analysis, going to be somewhere on the graph where the lines occupy the exact same coordinates on one plane. They will occupy it at different "times" (mileages) ..but THEY WILL BE AT THE SAME LEVELS IN CONCENTRATION.
I'm saying that you're (typically) draining your oil before EITHER of those levels are damaging to your engine. If you're a 3k/3m prisoner ...you've (most likely) got more active zddp than someone running SL out to a sensible OCI.
If you can throw a bucket of water on that notion ..I'll end my contributions to this minor matter (imo). I have enjoyed, and do admire, your apparent ability to find only that which tends to support this notion and your complete rejection of offered, anxiety easing, information. A tip of the hat to you, sir
Cheers