All ATF is full synthetic as far as I know.
As for speed sensors, here's the answer once and for all.
The VSS on 91-01 XJs is ONLY FOR THE ECU AND SPEEDO. The TCU doesn't see it. It's in the trans tailhousing next to the OSS on 2wd XJs, it's in the tcase tailhousing on 4wd XJs.
The one you refer to is the OSS, output speed sensor. It reads the trans output shaft speed. The ECU never sees this one, but the TCU does and uses it to determine what gear it should be in.
The other one no one mentioned is the ISS, input speed sensor. It reads the trans input shaft speed *after* the torque converter, and is only present on 98-01 4.0L XJs. The TCU gets this info, again, and the ECU does not.
e: counts per turn and per mile:
ISS: 16 pulses per trans input shaft revolution.
OSS: 98-01 4 pulses per trans output shaft revolution. 87-97 1 pulse per trans output shaft revolution.
VSS: 8000 pulses per mile, 8 pulses per VSS input gear rotation. The speedo gear is selected so that the 13-tooth worm gear on the output shaft of the transfer case will turn it 1000 times per mile, then each of those 1000 rotations is converted to 8 pulses by the VSS.
The reason to have a VSS and an OSS is because the TCU and ECU don't know if the transfer case is in low range or not, or what its ratio is. So trans output speed and driveshaft speed aren't necessarily the same. Both are stuck in the back of a 2wd XJ's transmission simply because it's easier to keep the electronics unaware of all of this and feed them the same signals on 2wd vs 4wd than it is to account for it in hardware/software and significantly complicate things.