Clutch change won't require anything be done to the transfer case. However, if there is anything you think you should do while it's out then now it the time. Chains are a wear item and will stretch. They last a long time but your Jeep is 26 yr old. If you hardly use 4WD it may be fine. If you use 4WD a lot it might be a good time to at least replace the chain.
I am doing a 4WD conversion to an XJ. I'll give the transfer case a full rebuild and also put on a slip yoke eliminator before I install. I'm at a position where I can afford some extravigances and have the space, tools and time to do most work like this. At other moments in my life I would run what I had if it wasn't causing problems yet because I had not the disposable income, time, tools or space. If this is your daily driver then you need to get back on the road ASAP. Bare minimum time and expense.