Overdoing the silicon on the gasket can squirt some silicon into the thermostat and cause issues, I use a very thin coat. The thermostat sits in a slight recess, if it slips out of the recess while you are tightening the bolts, it may slip down and the rim of the thermostat is likely to warp the thermostat housing. I believe, but I'm not really sure, the bolts for the thermostat housing are two different lengths. I may be wrong and have it confused with another vehicle.
Some time back (years) my son was helping on the Jeep, I handed him my smeared up thermostat housing gasket and told him not to over tighten the bolts, the housing is aluminum. I figured start him out small and let him work his way up to the major jobs. Six-eight months after, I noticed one bolt was gone and the other screwed out maybe three threads. I remember thinking, I did tell him not to over tighten them but this is ridiculous and I forgot to tell him to use Loc Tite. Lessons like this I learned the hard way, usually by getting stuck someplace. But smearing up both sides of the gasket did work well, the thermostat housing still wasn't leaking.
I really don't know what happened, my son is a pain to work with, between answering his cell phone, pee breaks, snack breaks and getting side tracked I wouldn't trust my life to his automotive mechanic abilities.

He usually tends to muscle brain things apart and together where finesse is called for.

I really don't know if those bolts do back out of there or not, to tell you the truth, but since then I Loc Tite them in there religiously.