Well, somebody has to say it...
The biggest performance gains you can get on most vehicles will be... a good tune up.
Before you spend money on after market parts or porting the head, be sure you:
Replace cap, rotor, wires & plugs
Make sure your catalytic converter is in good shape
Replace O2 sensors as necessary
Clean the TB
Replace fuel filter, if applicable, and make sure the pump is healthy
have a fresh air filter
Run some injector cleaner (I've used Sea Foam, though I hear BGK44 is good stuff as well)
ETC
On my rig, replacing the worn-out cat did a lot more than anything else I messed with