Yeah, I've done a LOT of research into HHO, and was working on building a PROPER setup into my Cherokee a year or two ago. There are a few major obstacles.
1. Hydrogen supply. Hydrogen generators supply H and O2, sure, but there is no metering for it. The way this needs to be properly done is to have a huge bottle of H in your vehicle, just like you keep gasoline.
2. Tuning. The reason HHO theoretically can work is because of the speed of the flame front being increased dramatically. It allows for highly retarded ignition timing and the goal here (this is where the mpg comes from) is to be able to run an ultra-lean fuel condition safely. There is no "kit" on the market I've ever seen that even attempts to use hho in any way that isn't some sort of quasi-science.
These kits remind me of how a lot of people think that oxygen is flammable. They take one little observation and make claims that they say are based on sound science. They aren't, and oxygen isn't flammable. It's a catalyst. There is a huge difference.
I've also worked on alternative fuel projects for Ford and we were building PURELY hydrogen powered buses. The only way we could even get those things to run was to supercharge them. Hydrogen doesn't have the same energy capacity per molecule as do the hydrocarbons we burn. You have to compound and compress the shit out of it to get an explosion in the chamber that is equivalent to gasoline.
Anyway those kits can get SOME results just by introducing H into the fuel stream, but they are incapable of really taking advantage of the hydrogen. You are rolling the dice with the exact setup you have, the random-ass amount of H and O2 made by the generator being supplied to the fuel mix, where your throttle happens to be at any given time, etc, etc... There are gains that can be had, sure, but...