There was a time I was working a job on which the commute was exactly 90 miles driveway to parking spot. A little more than 80 of those miles was on I-80, the rest a smaller, good two-lane. The straightest shot possible. Two round-trips per tank. Only four start-up cycles. Fill-up every other day, no evaporation. At or slightly under the 65MPH speed limit, traffic permitting, cruise as much as I could. In other words, the most ideal trip (if you don't mind commuting three hours a day!). I was getting just over 23 MPG, of 87 octane, no ethanol gas. That's the best I've ever seen in any of our XJs.
Remember, XJ's were rated by the EPA as 15/19 city/highway (I have the window sticker to my '96 Country). Most folks don't usually hit those numbers. Remember, just recently, they were downgraded, most vehicles by about 10%. That would put my '96 at 17MPG. I usually get a little over 20 with it, so I guess I'm doing OK!